Three copper sulphide leaching and refining processes are discussed: total pressure oxidation, ferric sulphate leaching and copper chloride leaching. The effect of mineralogy on the choice of processing technology is discussed as well as some of the unit processes used.
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Leaching copper oxides at pH > 10.5 was the optimum to ensure copper(II) glycinate stability and to achieve maximum copper extraction. Table 8 shows the percentage of copper extracted from the copper oxide minerals under optimum conditions of pH 11, glycine to copper ratio of 4:1 and ambient temperature.
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Typical copper electrolyte solution produced from leaching of copper ore, contains 25–60 g/L of copper and 0.1–10 g/L of iron in the electrowinning stage (Evans, 2003; Habashi, 1998). These industrial processes operate in temperatures of 40–60 °C, pH of 1 and current densities in the range of 20–45 mA/cm 2 are used ( Moats and Free, 2007 ).
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LEACHING COPPER SULFIDES A survey of the literature reveals numerous methods which have been proposed for the leaching of copper sulfides. Few of these have been carried beyond the laboratory stage, and none are used commercially to produce metallic copper. Much work is presently being carried out on hydro-
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TECHNOLOGY OPTIONS AND INNOVATION FOR COPPER HEAP LEACHING If you would like a full copy including photos, tables etc send request to: [email protected] *Damian Connelly Mineral Engineering
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